Fig. 3 Macro X-Ray fluorescence (MA-XRF) scan showing the presence of paint containing mercury beneath the composition of the indigo dyers.
Fig. 4 The same image rotated 180 degrees, revealing a pair of legs and feet.
The Mesdag Collection in The Hague is the only public collection in the Netherlands to hold a work by the American painter John Singer Sargent (1856–1925). Blue plays a prominent role in the painting, a study of three indigo dyers dressed in deep blue, with traces of indigo dye on the cloth they carry, and their hands and forearms. This ancient craft had a long tradition in Egypt, where Sargent spent some time in 1891.
This raises the question of whether the artist himself also used indigo in the painting. Egyptian Indigo Dyers was treated at the conservation studio in Amsterdam, while analysis of the pigments used produced some unexpected results.
Removing the surface dirt and yellowed varnish brought out the painting’s many variations in colour. The different shades of white, blue and green as well as the purple and pink accents, now come into their own. The highly varied, fluid brushwork characteristic of Sargent’s approach to plein-air sketching is also much more apparent (fig. 1).
Varnish removal also revealed fingerprints along the edges, probably left when the canvas was moved while the paint was still wet (fig. 2). After old retouching was removed, other impressions in the paint became more clearly visible. These were probably left when the painting accidentally leant against something.
The paint surface itself contains numerous dust particles that became embedded before the paint had dried. All these traces shed light on Sargent’s working process, suggesting he worked quickly and handled the painting before allowing it to dry.
The dyers depicted in the painting used organic indigo to dye textiles. Obtaining this dye was a time-consuming process requiring specialist knowledge. In the last quarter of the 19th century, synthetic indigo was also developed and subsequently found its way into the paint industry.
During treatment, this raised the question of which blue paint Sargent had used for the colour that plays such an important role in the composition. Could he have used synthetic indigo? And if not, which blue did he use?
Tubes labelled ‘indigo’ have been found in one of Sargent’s paint boxes, but it is not known what they actually contain or whether he took this colour with him on his trip to Egypt. To analyse the blue in Egyptian Indigo Dyers, the painting was examined using a scanning macro X-Ray fluorescence (MA-XRF) scanner.
This technique detects a number of chemical elements that can provide an indication of the pigments present in the paint. The results show that Sargent at least used cobalt blue and ultramarine blue in this painting.
The ground was found to consist primarily of white lead. Two types of organic red were also used, as well as umber, ochres, bone or ivory black, an unidentified purple and chromium oxide green. This range of pigments is consistent with previous research into Sargent’s use of colour but may not provide a complete picture. Purple pigment grains were also observed in the painting using a stereomicroscope.
Other analytical methods would be needed to identify these and to confirm or rule out the presence of other possible blue pigments, such as indigo and Prussian blue. For the time being, it was decided not to pursue these further analyses.
The MA-XRF scan did, however, yield another remarkable discovery. The image produced by the scanner revealed an unusual shape in the distribution of mercury (Hg) (fig. 3). The only pigment containing mercury is the red pigment vermilion, but this colour does not occur in the composition of Egyptian Indigo Dyers. Rotating the scan by 180 degrees revealed that the unusual shape consists of two legs and feet, with part of a hand visible at the top (fig. 4).
Fig. 3 Macro X-Ray fluorescence (MA-XRF) scan showing the presence of paint containing mercury beneath the composition of the indigo dyers.
Fig. 4 The same image rotated 180 degrees, revealing a pair of legs and feet.
The painting had previously also been examined using infrared reflectography, a technique in which infrared radiation can reveal underlying paint layers. This confirmed that the shape is the lower part of a standing figure, dressed in what appears to be a short cloak. The composition was laid in using thin layers of paint with little detail.
An infrared reflectogram of the reverse of the painting also revealed a stamp from the artist’s supplier where Sargent purchased the prepared canvas. However, rather than being positioned symmetrically, as was customary at the time, the stamp was located towards one side.
Taken together, these findings suggest that Sargent cut a canvas bearing an existing, probably unfinished composition into pieces, then turned the lower section around and reused it to paint Egyptian Indigo Dyers while in Egypt.
A search for the source of the underlying composition led to copies Sargent made after works by Velázquez (1599–1660) during visits to the Prado Museum in Madrid in 1879. The legs and short cloak in Velázquez’s The Buffoon Don Juan de Austria bear a strong resemblance to those in the underlying composition (fig. 5).
Sargent’s copy of the buffoon’s head (fig. 6) is now in a private collection in France. The composition beneath Egyptian Indigo Dyers, however, is a mirror image of Velázquez’s original.
Could this be a previously unknown copy made after Sargent’s return from Madrid? Or perhaps a later portrait painted in the Spanish style? The search for Sargent’s blue pigments thus raised a whole range of new questions extending far beyond the colour blue.
Fig. 5 Diego Velázquez, The Buffoon Don Juan de Austria, 1632. Oil on canvas, 210 × 124.5 cm. Museo del Prado, Madrid.
Fig. 6 John S. Sargent, The Buffoon Don Juan de Austria, after Velázquez, 1879. Oil on canvas, 52.1 × 41.9 cm. Private collection, Paris.
Ana Martins, Heritage Scientist in the Research Department at the Van Gogh Museum, was responsible for the scanning and interpretation of the analytical results.